Crystal structure of bis(2,2’-bipyridine-N,N’)-[1,10-phenanthroline-5,6-dione]ruthenium(II) dihexafluorophosphate acetone solvate, [Ru(C10H8N2)2(C12H6N2O2)][PF6]2 · 1.75(CH3)2CO
نویسندگان
چکیده
منابع مشابه
Bis(2,2′-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate
The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline liga...
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The complex cation of the title compound, [Co(C12H8N2)3]2(NO3)4·C12H12N2O6·8H2O, contains a Co(II) atom with a distorted octa-hedral coordination environment defined by six N atoms from three bidentate 1,10-phenanthroline ligands. The asymmetric unit of the title compound is completed by one-half of the N,N'-(1,4-phenyl-enedicarbon-yl)diglycine solvent mol-ecule, which is located on a centre of...
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Surface defects are known to dominate both the electronic and chemical properties of metal oxide surfaces, an object of much study for use in catalytic processes. In order to study surface chemistry in detail, an ultra-high vacuum (UHV) chamber was designed to combine a LEED and STM system. Construction is underway, with a reported initial base pressure of 10−9 Torr revealing no major leaks. On...
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The structure of the title compound, C11H15N3OS, shows the flexibility due to the methyl-ene group at the thio-amide N atom in the side chain, resulting in the mol-ecule being non-planar. The dihedral angle between the plane of the benzene ring and that defined by the atoms of the thio-semicarbazide arm is 79.847 (4)°. In the crystal, the donor-acceptor hydrogen-bond character of the -OH group ...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2002
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.2002.217.jg.571